The Champions League continues on Tuesday and Wednesday with Matchday 4.
Club Brugge and Union Saint-Gilloise will face two Spanish giants: FC Barcelona and Atlético Madrid. It will be a tough challenge for the two Jupiler Pro League sides, who need points if they want to stay alive in this competition.
Discover our predictions for some of these fixtures along with the best bet on football odds to guide your sports bets.
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Champions League 2025/26: Matchday 4 Betting Tips
All odds are subject to change
Atlético Madrid to score in both halves vs Union Saint-Gilloise @ 1.75
Diego Simeone’s men have already suffered two defeats in this competition, both against English clubs. The Madrilenians view this match as the perfect opportunity to collect points and climb back up the table. As we know, Atlético are almost unbeatable at home: Antoine Griezmann and his teammates have won 5 of their 6 home matches in all competitions this season. USG, still leaders in the Pro League, have endured back-to-back heavy defeats in the Champions League and will have to face the determination of the Spaniards, who must win to keep their top-8 hopes alive.
Liverpool vs Real Madrid: Kylian Mbappé to score anytime @ 1.83
This thrilling clash between two European giants should live up to expectations. Real Madrid have a perfect record so far in the Champions League, thanks in large part to French star Kylian Mbappé, who has already scored 5 goals in 3 matches. Facing a Liverpool side low on confidence and with a fragile defence, the France captain could once again use his pace and explosiveness to add to his tally.
Paris SG vs Bayern Munich: Draw @ 4.05
One of the highlights of Matchday 4. PSG and Bayern Munich are both unbeaten in this competition and have lived up to their favourite status. The Parisians are coming off a stunning 7-2 win over Bayer Leverkusen but have been struggling more in Ligue 1. Ousmane Dembélé and his teammates have been held to three draws in their last four league matches (Lille 1-1, Strasbourg 3-3, Lorient 1-1) but did pick up a valuable 1-0 win at Nice in their most recent outing. Bayern continue to rack up wins and remain undefeated in all competitions. Despite Vincent Kompany’s team looking impressive, this trip to Paris will be their first real test of the season. We expect a draw between Europe’s two best sides.
Club Brugge vs FC Barcelona: Both teams to score @ 1.42
On paper, Barcelona should win this match comfortably, but we expect a tighter contest. This season, Hansi Flick’s side have been unpredictable, mixing strong performances with weaker ones. Meanwhile, Club Brugge are battling with Union Saint-Gilloise for the top spot in Belgium. Even though they have lost 2 of their 3 Champions League matches so far, Christos Tzolis and his colleagues have quality and can certainly score at least once against a Barcelona defence that has looked shaky at times.
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